polymerisation

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polymerisation

A scientist observes polymerisation in a beaker.

Definition
  1. Noun:
    • A chemical process that combines several monomers to form a polymer or polymeric compound: Polymerisation is a reaction in which small, simple molecules (monomers) link together to form a large, chain-like or network molecule (a polymer).
Usage
  • The term "polymerisation" is used to describe the fundamental chemical reaction in creating plastics, synthetic fibers, and many biological macromolecules. It is a standard term in chemistry, materials science, and industrial manufacturing.
Examples
  • Noun:
    • The polymerisation of ethylene produces polyethylene, a common plastic.
    • Controlling the rate of polymerisation is crucial for determining the properties of the final material.
    • Vinyl chloride undergoes polymerisation to form polyvinyl chloride (PVC).
Advanced Usage
  • "Chain-growth polymerisation": A type of polymerisation where monomers add to a growing chain one at a time, typical for polymers like polyethylene and polystyrene.

    • Free-radical polymerisation is a common mechanism for chain-growth polymerisation.
  • "Step-growth polymerisation": A type of polymerisation where monomers with reactive end groups react together in steps, typical for polymers like nylon and polyester.

    • The synthesis of this resin involves a step-growth polymerisation reaction.
Variants and Related Words
  • Polymerize (verb): To undergo or cause to undergo polymerisation.

    • These monomers will polymerize rapidly under heat.
  • Polymer (noun): The large molecule formed by the polymerisation of monomers.

  • Monomer (noun): The small molecule that serves as the building block for a polymer.
Synonyms
  • Polymerization (alternative spelling, primarily US English)
  • Polycondensation (specifically for a polymerisation reaction that releases a small molecule like water as a byproduct)
Related Phrases
  • "Initiation of polymerisation": The step that starts the polymerisation reaction, often involving an initiator molecule.
  • "Degree of polymerisation": The number of monomeric units in a polymer molecule.
polymerisation

A scientist observes polymerisation in a beaker.

Noun
  1. a chemical process that combines several monomers to form a polymer or polymeric compound

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