alicyclic compound
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Definition
Noun: * An organic compound that is both aliphatic (having properties similar to open-chain hydrocarbons) and cyclic (containing a ring of atoms). The ring is typically composed of carbon atoms, but unlike aromatic compounds (e.g., benzene), it does not have a continuous, overlapping ring of p-orbitals and exhibits properties closer to alkanes or alkenes.
Usage
- The term classifies a major category of organic structures based on the type of carbon skeleton.
- It is used to distinguish these saturated or unsaturated non-aromatic ring systems from purely open-chain (acyclic) aliphatic compounds and from aromatic compounds.
Examples
- Cyclohexane is a simple .
- The chemist synthesized a novel with a five-membered ring.
- Many natural products, such as certain terpenes, contain in their structure.
Advanced Usage
- Bridged and Fused Rings: Complex can include bridged ring systems (like norbornane) or fused rings (like decalin), where multiple rings share atoms.
- Heterocyclic Analogues: While the classic definition involves carbon rings, the term is sometimes extended to non-aromatic rings containing heteroatoms (like oxygen or nitrogen) if their chemical behavior is aliphatic in nature.
Variants and Related Words
- Alicyclic (adjective): Describing the characteristic of such compounds.
- Example: "The molecule has an alicyclic ring system."
- Cycloalkane (noun): A specific type of alicyclic compound where the ring contains only single bonds (saturated).
- Cycloalkene (noun): A specific type of alicyclic compound containing at least one carbon-carbon double bond within the ring.
Different Meanings
This term has a single, specific meaning in the field of organic chemistry. It does not have common alternative definitions in general language.
Synonyms
- Non-aromatic cyclic compound
- Aliphatic cyclic compound
- Carbocyclic compound (when specifying rings of only carbon atoms, and if non-aromatic)
Antonyms
- Acyclic compound (open-chain compound)
- Aromatic compound (e.g., benzene, pyridine)
Related Phrases / Collocations
- Alicyclic ring: Refers specifically to the cyclic portion of the molecule.
- Example: "The reactivity is determined by the strain in the alicyclic ring."
- Alicyclic chemistry: The subfield of organic chemistry dealing with these compounds.
- Saturated alicyclic compound: An alicyclic compound with only single bonds in the ring (a cycloalkane).
Noun
- an aliphatic compound that contains a ring of atoms