allomerism
/ə'lɔmərizm/
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Definition
Noun: 1. Variability in chemical composition without variation in crystalline form: In chemistry, allomerism refers to the phenomenon where two or more substances have different chemical compositions but share the same crystalline structure.
Usage
- General Usage: The term is used specifically in the field of chemistry and mineralogy to describe compounds that are isomorphous (have the same crystal shape) but differ in their elemental makeup.
- The study of allomerism helps geologists understand how different minerals can form in the same crystal habit.
Examples
- Noun:
- The two minerals exhibit allomerism; one is a calcium carbonate and the other is a strontium carbonate, yet they crystallize in identical forms.
- Allomerism is a key concept when analyzing solid solutions in mineral series.
Advanced Usage
- In Scientific Context: The concept is often discussed in relation to isomorphism and solid solution series.
- The allomerism observed in the feldspar group is due to the substitution of sodium for calcium within the crystal lattice.
Variants and Related Words
- Allomeric (adj): Pertaining to or characterized by allomerism.
- The allomeric relationship between the two samples was confirmed by X-ray diffraction.
Synonyms
- Isomorphism (in a specific, related sense, though isomorphism emphasizes the same form, while allomerism emphasizes the different composition within that form).
- Isomorphous replacement.
Antonyms
- Polymorphism: The phenomenon where a substance can exist in more than one crystalline form.
Noun
- (chemistry) variability in chemical composition without variation in crystalline form