cross-linkage

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cross-linkage

A scientist points to a diagram showing cross-linkage in a polymer structure.

Definition

Noun: 1. A chemical bond that connects one polymer chain to another: In chemistry and materials science, a cross-linkage is a bond, atom, or short chain of atoms that links two longer chains (polymer chains) in a complex molecule or material. This connection creates a networked structure, altering the physical properties of the material, such as making it harder, more rigid, or less soluble.

Usage and Examples
  • Noun:
    • The vulcanization of rubber involves the formation of cross-linkages between polymer chains, making it more elastic and durable.
    • The strength of the gel is due to the numerous cross-linkages within its structure.
    • Scientists studied the cross-linkage in the protein to understand its stability.
Advanced Usage
  • In Biochemistry: Refers to bonds connecting different parts of a biomolecule (like DNA or proteins), which can affect function and structure.
    • DNA cross-linkage can be caused by certain chemicals and may interfere with replication.
  • In Materials Science: Describes the intentional creation of links to modify material properties.
    • Controlling the degree of cross-linkage is key to designing polymers with specific characteristics.
Variants and Related Words
  • Cross-link (noun/verb): The bond itself or the act of forming such bonds. Often used interchangeably with "cross-linkage."
    • The cross-links in the resin make it thermoset. (Noun)
    • The agent helps cross-link the polymers. (Verb)
  • Cross-linked (adjective): Describes a material that has undergone this process.
    • Cross-linked polyethylene (PEX) is used in plumbing.
Synonyms
  • Cross-bond: A less common synonym emphasizing the bonding aspect.
  • Network bond: A descriptive term highlighting the resulting interconnected structure.
Related Phrases and Concepts
  • Cross-linking agent (or cross-linker): A substance that facilitates the formation of cross-linkages.
    • Divinylbenzene is a common cross-linking agent in polymer chemistry.
  • Degree of cross-linking: A measure of how many cross-linkages are present in a material.
    • A higher degree of cross-linking typically increases the material's melting point.
cross-linkage

A scientist points to a diagram showing cross-linkage in a polymer structure.

Noun
  1. a side bond that links two adjacent chains of atoms in a complex molecule

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