enolic
Học thuậtThân thiện
Definition
- Adjective:
- Relating to or consisting of enol: Pertaining to the chemical structure or properties of an enol, which is an organic compound characterized by a hydroxyl group (-OH) attached to a carbon atom that is part of a carbon-carbon double bond.
Usage Examples
- Adjective:
- The keto-enol tautomerism involves the interconversion between a ketone and its enolic form.
- The enolic hydrogen is more acidic than typical alcohol hydrogens.
- This compound exhibits enolic properties under basic conditions.
Advanced Usage
- "Enolic character": Refers to the degree to which a molecule exhibits the properties or structure of an enol.
- The molecule's high enolic character explains its reactivity in this reaction.
- "Enolic tautomer": Specifically denotes the enol form of a compound that exists in equilibrium with a keto form.
- In this equilibrium, the enolic tautomer is less stable but more reactive.
Variants and Related Words
- Enol (noun): The unsaturated alcohol compound itself, with the structure R-C(OH)=CR₂.
- The formation of an enol is a key step in many organic reactions.
- Enolate (noun): The anionic conjugate base derived from an enol, typically formed by deprotonation.
- The enolate ion is a common nucleophile in synthesis.
Synonyms
- Olefinic alcohol-related: (Descriptive synonym) Pertaining to the alcohol derivative of an alkene.
Notes on Meaning
- The term "enolic" is a specialized adjective used almost exclusively in the field of organic chemistry. It does not describe a standalone substance but rather the nature, properties, or a specific form (tautomer) of a compound. Its meaning is directly and solely derived from the noun "enol".
Adjective
- of or relating to or consisting of enol